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More attraction means more closeness

2/27/2016

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atom radius size proton number electron number
To answer last post's question of why the atomic radii shrink as more protons are added left to right on the periodic table, let’s again focus on the opposing charges between protons and electrons within an atom. Since these particles of opposing charges attract each other, they pull on each other. This is more so the case of protons pulling on electrons since a proton’s mass is so much greater than an electron’s negligible mass.

In the case of the decreasing atomic radii for periods, as one more proton is added, a greater positive force per additional proton is exerted on the negligible negative force from the additional electron. This collective attractive force contributed by a proton particle of more substantial mass than its electron counterpart, is capable of pulling the electrons closer to its center, thereby contracting the overall dimension of the atom.

So, why do the atomic dimensions increase in groups? Significant increases in proton attractive force are occurring, so yes, collective proton charge is also increasing...but so too are the repulsive forces among the very crowded electrons. And take a look at the figure: there is an increasing DISTANCE from the nucleus to the farthest flung electrons, effectively diminishing that proton attractive force. The repulsive forces therefore take over, the electrons spread out as much as possible, and to accommodate this the atomic dimension also expands!

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